Upperseven The Man to Kill (1966) The Spy with 10 Faces

Rosalba plays a bad girl trying to trap the Bond knock off who just took her to bed.  He is on to her though and uses her as a decoy to lure the killers out in the open.  Rosalba gets to play guitar and sing a song, and then eat lead.  Another in her endless series of brief supporting roles.